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A Self-Assembled Electro-Active M8L4 Cage Based on Tetrathiafulvalene Ligands.

ABSTRACT: Two self-assembled redox-active cages are presented. They are obtained by coordination-driven self-assembly of a tetra-pyridile tetrathiafulvalene ligand with cis-M(dppf)(OTf)? (M = Pd or Pt; dppf = 1,1'-bis(diphenylphosphino)ferrocene; OTf = trifluoromethane-sulfonate) complexes. Both species are fully characterized and are constituted of 12 electro-active subunits that can be reversibly oxidized.

SUBMITTER: Goeb S 

PROVIDER: S-EPMC5453136 | biostudies-literature | 2014 Jan

REPOSITORIES: biostudies-literature

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A Self-Assembled Electro-Active M8L4 Cage Based on Tetrathiafulvalene Ligands.

Goeb Sébastien S   Bivaud Sébastien S   Croué Vincent V   Vajpayee Vaishali V   Allain Magali M   Sallé Marc M  

Materials (Basel, Switzerland) 20140122 1

Two self-assembled redox-active cages are presented. They are obtained by coordination-driven self-assembly of a tetra-pyridile tetrathiafulvalene ligand with cis-M(dppf)(OTf)₂ (M = Pd or Pt; dppf = 1,1'-bis(diphenylphosphino)ferrocene; OTf = trifluoromethane-sulfonate) complexes. Both species are fully characterized and are constituted of 12 electro-active subunits that can be reversibly oxidized. ...[more]

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