Ontology highlight
ABSTRACT:
SUBMITTER: Goeb S
PROVIDER: S-EPMC5453136 | biostudies-literature | 2014 Jan
REPOSITORIES: biostudies-literature
Goeb Sébastien S Bivaud Sébastien S Croué Vincent V Vajpayee Vaishali V Allain Magali M Sallé Marc M
Materials (Basel, Switzerland) 20140122 1
Two self-assembled redox-active cages are presented. They are obtained by coordination-driven self-assembly of a tetra-pyridile tetrathiafulvalene ligand with cis-M(dppf)(OTf)₂ (M = Pd or Pt; dppf = 1,1'-bis(diphenylphosphino)ferrocene; OTf = trifluoromethane-sulfonate) complexes. Both species are fully characterized and are constituted of 12 electro-active subunits that can be reversibly oxidized. ...[more]