Ontology highlight
ABSTRACT:
SUBMITTER: Li Z
PROVIDER: S-EPMC3413634 | biostudies-literature | 2012 Jul
REPOSITORIES: biostudies-literature
Li Zhanjie Z Parr Brendan T BT Davies Huw M L HM
Journal of the American Chemical Society 20120625 26
The tandem ylide formation/[2,3]-sigmatropic rearrangement between donor/acceptor rhodium carbenoids and chiral allyl alcohols is a convergent C-C bond forming process, which generates two vicinal stereogenic centers. Any of the four possible stereoisomers can be selectively synthesized by appropriate combination of the chiral catalyst Rh(2)(DOSP)(4) and the chiral alcohol. ...[more]