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Potassium morpholine-4-carbodithio-ate monohydrate.

ABSTRACT: In the ionic title compound, K(+)·C(5)H(8)NOS(2) (-)·H(2)O, the morpholine ring of the morpholine-4-carbodithio-ate anion has a chair conformation. The potassium cation is coordinated by four S and four O atoms in a bipyramidal reversed geometry. In the crystal, the three components are linked, generating infinite two-dimensional networks that lie parallel to the bc plane. These layers are linked via O-H?S hydrogen bonds, forming a three-dimensional structure.

SUBMITTER: Mafud AC

PROVIDER: S-EPMC3414100 | biostudies-literature | 2012 Aug

REPOSITORIES: biostudies-literature

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Potassium morpholine-4-carbodithio-ate monohydrate.

Mafud Ana C AC Gambardella Maria Teresa Prado MT

Acta crystallographica. Section E, Structure reports online 20120704 Pt 8

In the ionic title compound, K(+)·C(5)H(8)NOS(2) (-)·H(2)O, the morpholine ring of the morpholine-4-carbodithio-ate anion has a chair conformation. The potassium cation is coordinated by four S and four O atoms in a bipyramidal reversed geometry. In the crystal, the three components are linked, generating infinite two-dimensional networks that lie parallel to the bc plane. These layers are linked via O-H⋯S hydrogen bonds, forming a three-dimensional structure. ...[more]

PMID: 22904707

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