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[N,N'-Bis(2,3,4-trimeth-oxy-benzyl-idene)-ethane-1,2-diamine-?(2)N,N']dibromido-mercury(II).


ABSTRACT: In the title compound, [HgBr(2)(C(22)H(28)N(2)O(6))], the Hg(II) ion is bonded to two Br(-) ions and two N atoms of the chelating Schiff base ligand in a distorted tetra-hedral geometry. The Schiff base ligand adopts an E,E conformation. The dihedral angle between the planes of the two halves of the central N,N'-dimethyl-ethylenediamine part of the ligand is 2.3?(11)°. The crystal studied was twinned by pseudomerohedry [twin law (0-10/-100/00-1)]; the contribution of the minor twin component refined to 0.208?(3).

SUBMITTER: Khalaji AD 

PROVIDER: S-EPMC3414113 | biostudies-literature | 2012 Aug

REPOSITORIES: biostudies-literature

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[N,N'-Bis(2,3,4-trimeth-oxy-benzyl-idene)-ethane-1,2-diamine-κ(2)N,N']dibromido-mercury(II).

Khalaji Aliakbar Dehno AD   Dušek Michal M   Fejfarová Karla K  

Acta crystallographica. Section E, Structure reports online 20120710 Pt 8


In the title compound, [HgBr(2)(C(22)H(28)N(2)O(6))], the Hg(II) ion is bonded to two Br(-) ions and two N atoms of the chelating Schiff base ligand in a distorted tetra-hedral geometry. The Schiff base ligand adopts an E,E conformation. The dihedral angle between the planes of the two halves of the central N,N'-dimethyl-ethylenediamine part of the ligand is 2.3 (11)°. The crystal studied was twinned by pseudomerohedry [twin law (0-10/-100/00-1)]; the contribution of the minor twin component ref  ...[more]

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