Unknown

Dataset Information

0

Dibromido[N-propyl-N'-(2-pyridylmethyl-idene)ethane-1,2-diamine]zinc(II).

ABSTRACT: The title complex, [ZnBr(2)(C(11)H(17)N(3))], is a mononuclear zinc(II) compound derived from the Schiff base N-propyl-N'-(1-pyridin-2-ylmethyl-idene)ethane-1,2-diamine. The Zn(II) atom is five-coordinate, binding to the imine N, pyridine N, and amine N atoms of the Schiff base ligand and to two bromide anions in a distorted trigonal-bipyramidal coordination geometry. Adjacent mol-ecules are linked through inter-molecular N-H?Br hydrogen bonds, forming dimers.

SUBMITTER: Zhu XW 

PROVIDER: S-EPMC2962000 | biostudies-literature | 2008 Jul

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Dibromido[N-propyl-N'-(2-pyridylmethyl-idene)ethane-1,2-diamine]zinc(II).

Zhu Xue-Wen XW   Yang Xu-Zhao XZ  

Acta crystallographica. Section E, Structure reports online 20080731 Pt 8

The title complex, [ZnBr(2)(C(11)H(17)N(3))], is a mononuclear zinc(II) compound derived from the Schiff base N-propyl-N'-(1-pyridin-2-ylmethyl-idene)ethane-1,2-diamine. The Zn(II) atom is five-coordinate, binding to the imine N, pyridine N, and amine N atoms of the Schiff base ligand and to two bromide anions in a distorted trigonal-bipyramidal coordination geometry. Adjacent mol-ecules are linked through inter-molecular N-H⋯Br hydrogen bonds, forming dimers. ...[more]

Similar Datasets

Unknown [N,N'-Bis(2,3,4-trimeth-oxy-benzyl-idene)-ethane-1,2-diamine-?(2)N,N']dibromido-mercury(II).
| S-EPMC3414113 | biostudies-literature
Unknown Diiodido[N'-(2-methoxy-benzyl-idene)-N,N-dimethyl-ethane-1,2-diamine]zinc(II).
| S-EPMC2970288 | biostudies-literature
Unknown Dichlorido[N-(2-pyridylmethyl-idene)benzene-1,4-diamine]zinc(II).
| S-EPMC2979197 | biostudies-literature
Unknown (?-Ethane-1,2-diamine-?N:N')bis-[bis-(ethane-1,2-diamine-?N,N')zinc(II)] tetra-kis-(perchlorate).
| S-EPMC3009181 | biostudies-literature
Unknown [?-N,N'-Bis(2-pyridylmethyl-ene)ethane-1,2-diamine]bis-{aqua-[N,N'-bis-(2-pyridyl-methyl-ene)ethane-1,2-diamine]manganese(II)} tetra-kis(perchlorate).
| S-EPMC2983616 | biostudies-literature
Unknown Dichlorido{N-[1-(pyrazin-2-yl)ethyl-idene-κN]ethane-1,2-diamine-κN,N'}zinc.
| S-EPMC3246976 | biostudies-literature
Unknown Bis{N-methyl-N'-[1-(pyridin-2-yl)ethyl-idene]ethane-1,2-diamine}-zinc bis-(perchlorate).
| S-EPMC3212129 | biostudies-literature
Unknown {N-Methyl-N'-[1-(pyridin-2-yl)ethyl-idene]ethane-1,2-diamine-?N,N',N''}-bis(thio-cyanato-?N)zinc(II).
| S-EPMC3151752 | biostudies-literature
Unknown N,N'-Bis(3-methoxy-benzyl-idene)ethane-1,2-diamine.
| S-EPMC2960703 | biostudies-literature
Unknown N,N'-Bis(2-iodo-benzyl-idene)ethane-1,2-diamine.
| S-EPMC2959359 | biostudies-literature