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Cis-Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-?N(2))ethanamine-?N]palladium(II) dichloro-methane monosolvate.

ABSTRACT: In the title compound, [PdCl(2)(C(7)H(13)N(3))]·CH(2)Cl(2), the 2-(3,5-dimethyl-1H-pyrazol-1-yl)ethanamine ligand chelates the Pd(II) atom via two N atoms forming a six-membered ring resulting in a distorted square-planar metal coordination environment, highlighted by N-Pd-Cl angles of 172.63?(8) and 174.98?(9)°. In addition to N-H?Cl hydrogen bonds creating infinite chains along [001], several C-H?Cl inter-actions are observed in the crystal structure.

SUBMITTER: Obuah C

PROVIDER: S-EPMC3414152 | biostudies-literature | 2012 Aug

REPOSITORIES: biostudies-literature

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cis-Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN(2))ethanamine-κN]palladium(II) dichloro-methane monosolvate.

Obuah Collins C Darkwa James J Muller Alfred A

Acta crystallographica. Section E, Structure reports online 20120721 Pt 8

In the title compound, [PdCl(2)(C(7)H(13)N(3))]·CH(2)Cl(2), the 2-(3,5-dimethyl-1H-pyrazol-1-yl)ethanamine ligand chelates the Pd(II) atom via two N atoms forming a six-membered ring resulting in a distorted square-planar metal coordination environment, highlighted by N-Pd-Cl angles of 172.63 (8) and 174.98 (9)°. In addition to N-H⋯Cl hydrogen bonds creating infinite chains along [001], several C-H⋯Cl inter-actions are observed in the crystal structure. ...[more]

PMID: 22904759

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