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(E)-4-Amino-N'-(2-hy-droxy-5-meth-oxy-benzyl-idene)benzohydrazide monohydrate.

ABSTRACT: In the title compound, C(15)H(15)N(3)O(3)·H(2)O, the hydazide Schiff base mol-ecule shows an E conformation around the C=N bond. An intra-molecular O-H?N hydrogen bond makes an S(6) ring motif. The dihedral angle between the substituted phenyl rings is 23.40?(11)°. The water mol-ecule mediates linking of neighbouring mol-ecules through O-H?(O,O) hydrogen bonds into infinite chains along the a axis, which are further connected together through N-H?O hydrogen bonds, forming a two-dimensional network parallel to (001). C-H?O inter-actions aso occur.

SUBMITTER: Kargar H 

PROVIDER: S-EPMC3414187 | biostudies-literature | 2012 Aug

REPOSITORIES: biostudies-literature

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(E)-4-Amino-N'-(2-hy-droxy-5-meth-oxy-benzyl-idene)benzohydrazide monohydrate.

Kargar Hadi H   Kia Reza R   Tahir Muhammad Nawaz MN  

Acta crystallographica. Section E, Structure reports online 20120704 Pt 8

In the title compound, C(15)H(15)N(3)O(3)·H(2)O, the hydazide Schiff base mol-ecule shows an E conformation around the C=N bond. An intra-molecular O-H⋯N hydrogen bond makes an S(6) ring motif. The dihedral angle between the substituted phenyl rings is 23.40 (11)°. The water mol-ecule mediates linking of neighbouring mol-ecules through O-H⋯(O,O) hydrogen bonds into infinite chains along the a axis, which are further connected together through N-H⋯O hydrogen bonds, forming a two-dimensional netwo  ...[more]

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