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1,2-Bis[(2,2':6',2''-terpyridin-4'-yl)-oxy]ethane.

ABSTRACT: The title compound, C(32)H(24)N(6)O(2), has an inversion centre located at the mid-point of the central C-C bond of the diether bridging unit. The terminal pyridine rings are canted relative to the central pyridine ring, with dihedral angles of 12.98?(6) and 26.80?(6)°. The maximum deviation from the eight-atom mean plane, defined by the two bridging O and C atoms and the central pyridine ring, is 0.0383?(10)° for the N atom.

SUBMITTER: Nikolayenko VI

PROVIDER: S-EPMC3414310 | biostudies-literature | 2012 Aug

REPOSITORIES: biostudies-literature

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1,2-Bis[(2,2':6',2''-terpyridin-4'-yl)-oxy]ethane.

Nikolayenko Varvara I VI Akerman Matthew P MP Grimmer Craig D CD Reddy Desigan D

Acta crystallographica. Section E, Structure reports online 20120707 Pt 8

The title compound, C(32)H(24)N(6)O(2), has an inversion centre located at the mid-point of the central C-C bond of the diether bridging unit. The terminal pyridine rings are canted relative to the central pyridine ring, with dihedral angles of 12.98 (6) and 26.80 (6)°. The maximum deviation from the eight-atom mean plane, defined by the two bridging O and C atoms and the central pyridine ring, is 0.0383 (10)° for the N atom. ...[more]

PMID: 22904843

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