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2-(2,3-Dimethyl-anilino)benzohydrazide.

ABSTRACT: In the title compound, C(15)H(17)N(3)O, the dihedral angle between the benzene rings is 58.05 (9)°. The non-H atoms of the hydrazide group lie in a common plane (r.m.s. deviation = 0.0006 Å) and are close to coplanar with their attached benzene ring [dihedral angle = 8.02 (9)°]. An intra-molecular N-H⋯O hydrogen bond generates an S(6) ring motif in the mol-ecule, and a short intra-molecular contact (H⋯H = 1.88 Å) is also observed. In the crystal, mol-ecules are linked by pairs of N-H⋯N hydrogen bonds into inversion dimers. The crystal packing also features C-H⋯π inter-actions.

SUBMITTER: Fun HK

PROVIDER: S-EPMC3414975 | biostudies-literature | 2012 Aug

REPOSITORIES: biostudies-literature

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2-(2,3-Dimethyl-anilino)benzohydrazide.

Fun Hoong-Kun HK Chia Tze Shyang TS Elsaman Tilal T Attia Mohamed I MI Abdel-Aziz Hatem A HA

Acta crystallographica. Section E, Structure reports online 20120725 Pt 8

In the title compound, C(15)H(17)N(3)O, the dihedral angle between the benzene rings is 58.05 (9)°. The non-H atoms of the hydrazide group lie in a common plane (r.m.s. deviation = 0.0006 Å) and are close to coplanar with their attached benzene ring [dihedral angle = 8.02 (9)°]. An intra-molecular N-H⋯O hydrogen bond generates an S(6) ring motif in the mol-ecule, and a short intra-molecular contact (H⋯H = 1.88 Å) is also observed. In the crystal, mol-ecules are linked by pairs of N-H⋯N hydrogen ...[more]

PMID: 22904962

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