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1,2-Bis[(3,5-diphenyl-1H-pyrazol-1-yl)meth-yl]benzene.

ABSTRACT: The title compound, C(38)H(30)N(4), a potentially mono- and bidentate ligand, does not seem to form palladium complexes similar to other poly(pyrazol-1-ylmeth-yl)benzenes due to the large steric size of the phenyl substituents on the pyrazole rings. The pyrazole rings have a 21.09?(5)° angle between their mean planes and exhibit a trans-like geometry in which the in-plane lone pairs of electrons on the 2-N nitrogen atoms point in opposite directions.

SUBMITTER: Spencer LC 

PROVIDER: S-EPMC3415022 | biostudies-literature | 2012 Aug

REPOSITORIES: biostudies-literature

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1,2-Bis[(3,5-diphenyl-1H-pyrazol-1-yl)meth-yl]benzene.

Spencer Lara C LC   Guzei Ilia A IA   Segapelo Tebogo V TV   Darkwa James J  

Acta crystallographica. Section E, Structure reports online 20120728 Pt 8

The title compound, C(38)H(30)N(4), a potentially mono- and bidentate ligand, does not seem to form palladium complexes similar to other poly(pyrazol-1-ylmeth-yl)benzenes due to the large steric size of the phenyl substituents on the pyrazole rings. The pyrazole rings have a 21.09 (5)° angle between their mean planes and exhibit a trans-like geometry in which the in-plane lone pairs of electrons on the 2-N nitrogen atoms point in opposite directions. ...[more]

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