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Bis[N-benzyl-N-(2-phenyl-eth-yl)dithio-carbamato-?(2)S,S']lead(II).

ABSTRACT: The mol-ecule of the title compound, [Pb(C(16)H(16)NS(2))(2)], is located on a twofold rotation axis, which runs through the Pb(II) atom. The two dithio-carbamate ligands coordinate the metal in a pyramidal configuration through the S atoms. The two phenyl rings of each dithocarbamate ligand are aligned at a dihedral angle of 78.4?(1)°. The mol-ecular conformation is stabilized by intra-molecular C-H?S inter-actions.

SUBMITTER: Sathiyaraj E

PROVIDER: S-EPMC3435626 | biostudies-literature | 2012 Sep

REPOSITORIES: biostudies-literature

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Bis[N-benzyl-N-(2-phenyl-eth-yl)dithio-carbamato-κ(2)S,S']lead(II).

Sathiyaraj E E Thirumaran S S Selvanayagam S S

Acta crystallographica. Section E, Structure reports online 20120825 Pt 9

The mol-ecule of the title compound, [Pb(C(16)H(16)NS(2))(2)], is located on a twofold rotation axis, which runs through the Pb(II) atom. The two dithio-carbamate ligands coordinate the metal in a pyramidal configuration through the S atoms. The two phenyl rings of each dithocarbamate ligand are aligned at a dihedral angle of 78.4 (1)°. The mol-ecular conformation is stabilized by intra-molecular C-H⋯S inter-actions. ...[more]

PMID: 22969499

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