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Bis{N-benzyl-N-[2-(thio-phen-2-yl)eth-yl]di-thio-carbamato-?(2) S,S'}lead(II).

ABSTRACT: The mol-ecule of the title compound, [Pb(C14H14NS3)2], is located on a twofold rotation axis. The di-thio-carbamate anion S,S'-chelates to the Pb(II) atom, which shows a ?-trigonal-bipyramidal coordination. The thio-phene ring is disordered over two positions, the major component having 71.3?(7)% occupancy. The mol-ecular conformation is stabilized by intra-molecular C-H?S inter-actions.

SUBMITTER: Sathiyaraj E

PROVIDER: S-EPMC3793692 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

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Bis{N-benzyl-N-[2-(thio-phen-2-yl)eth-yl]di-thio-carbamato-κ(2) S,S'}lead(II).

Sathiyaraj E E Thirumaran S S Sridhar B B Selvanayagam S S

Acta crystallographica. Section E, Structure reports online 20130717 Pt 8

The mol-ecule of the title compound, [Pb(C14H14NS3)2], is located on a twofold rotation axis. The di-thio-carbamate anion S,S'-chelates to the Pb(II) atom, which shows a Ψ-trigonal-bipyramidal coordination. The thio-phene ring is disordered over two positions, the major component having 71.3 (7)% occupancy. The mol-ecular conformation is stabilized by intra-molecular C-H⋯S inter-actions. ...[more]

PMID: 24109279

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