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Bis-(2-hy-droxy-eth-yl)ammonium 2-bromo-phenolate.

ABSTRACT: In the crystal structure of the 1:1 title salt, C(4)H(12)NO(2) (+)·C(6)H(4)BrO(-), hydrogen-bonding inter-actions originate from the ammonium cation, which adopts a syn conformation. A gauche relationship between the C-O and C-N bonds of the 2-hy-droxy-ethyl fragments also facilitates O-H?O inter-actions of bis-(2-hy-droxy-eth-yl)ammonium cation chains to phenolate O atoms. The resulting double-ion chains along [100] are further linked by N-H?O inter-actions, forming chains parallel to [110].

SUBMITTER: Padayachy K

PROVIDER: S-EPMC3435641 | biostudies-literature | 2012 Sep

REPOSITORIES: biostudies-literature

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Bis-(2-hy-droxy-eth-yl)ammonium 2-bromo-phenolate.

Padayachy Kamentheren K Fernandes Manuel A MA Marques Helder M HM Lemmerer Andreas A de Sousa Alvaro S AS

Acta crystallographica. Section E, Structure reports online 20120801 Pt 9

In the crystal structure of the 1:1 title salt, C(4)H(12)NO(2) (+)·C(6)H(4)BrO(-), hydrogen-bonding inter-actions originate from the ammonium cation, which adopts a syn conformation. A gauche relationship between the C-O and C-N bonds of the 2-hy-droxy-ethyl fragments also facilitates O-H⋯O inter-actions of bis-(2-hy-droxy-eth-yl)ammonium cation chains to phenolate O atoms. The resulting double-ion chains along [100] are further linked by N-H⋯O inter-actions, forming chains parallel to [110]. ...[more]

PMID: 22969514

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