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Diaqua-bis-(1H-imidazole-4-carboxyl-ato-?(2)N(3),O)cobalt(II).

ABSTRACT: In the title compound, [Co(C(4)H(3)N(2)O(2))(2)(H(2)O)(2)], the Co(II) ion is located on a twofold rotation axis and shows a distorted octa-hedral coordination configuration, defined by two N,O-bidentate 1H-imidazole-4-carboxyl-ate ligands in the equatorial plane and two water mol-ecules in the axial positions. In the crystal, O-H?O and N-H?O hydrogen bonds link the mol-ecules into a three-dimensional supra-molecular network. ?-? stacking inter-actions between the imidazole rings [centroid-centroid distances = 3.4914?(15) and 3.6167?(15)?Å] further stabilize the crystal structure.

SUBMITTER: Chen WS

PROVIDER: S-EPMC3470135 | biostudies-literature | 2012 Oct

REPOSITORIES: biostudies-literature

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Diaqua-bis-(1H-imidazole-4-carboxyl-ato-κ(2)N(3),O)cobalt(II).

Chen Wen-Sen WS

Acta crystallographica. Section E, Structure reports online 20120908 Pt 10

In the title compound, [Co(C(4)H(3)N(2)O(2))(2)(H(2)O)(2)], the Co(II) ion is located on a twofold rotation axis and shows a distorted octa-hedral coordination configuration, defined by two N,O-bidentate 1H-imidazole-4-carboxyl-ate ligands in the equatorial plane and two water mol-ecules in the axial positions. In the crystal, O-H⋯O and N-H⋯O hydrogen bonds link the mol-ecules into a three-dimensional supra-molecular network. π-π stacking inter-actions between the imidazole rings [centroid-centr ...[more]

PMID: 23125579

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Diaqua-bis-(1H-imidazole-4-carboxyl-ato-?(2)N(3),O)cobalt(II).

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