Unknown

Dataset Information

0

Diaqua-bis(5-carb-oxy-2-methyl-1H-imidazole-4-carboxyl-ato-?N,O)cobalt(II) dimethyl-formamide disolvate.

ABSTRACT: In the title compound, [Co(C(6)H(5)N(2)O(4))(2)(H(2)O)(2)]·2C(3)H(7)NO, the Co(II) ion lies on an inversion center and adopts a slightly distorted CoN(2)O(4) octa-hedral geometry binding two bidentate chelating 5-carb-oxy-2-methyl-1H-imidazole-4-carboxyl-ate (H(2)MIDA(-)) monoanionic ligands and two axial aqua ligands. In the crystal structure, inter-molecular O-H?O hydrogen bonds link neighboring mol-ecules, generating a two-dimensional framework containing eight-membered H(4)O(4) rings. In addition, the dimethyl-formamide solvent mol-ecules are hydrogen bonded to the two-dimensional framework via the NH groups of the H(2)MIDA(-) ligands.

SUBMITTER: Tang SP 

PROVIDER: S-EPMC2977566 | biostudies-literature | 2009 Apr

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Diaqua-bis(5-carb-oxy-2-methyl-1H-imidazole-4-carboxyl-ato-κN,O)cobalt(II) dimethyl-formamide disolvate.

Tang Si-Ping SP  

Acta crystallographica. Section E, Structure reports online 20090410 Pt 5

In the title compound, [Co(C(6)H(5)N(2)O(4))(2)(H(2)O)(2)]·2C(3)H(7)NO, the Co(II) ion lies on an inversion center and adopts a slightly distorted CoN(2)O(4) octa-hedral geometry binding two bidentate chelating 5-carb-oxy-2-methyl-1H-imidazole-4-carboxyl-ate (H(2)MIDA(-)) monoanionic ligands and two axial aqua ligands. In the crystal structure, inter-molecular O-H⋯O hydrogen bonds link neighboring mol-ecules, generating a two-dimensional framework containing eight-membered H(4)O(4) rings. In add  ...[more]

Similar Datasets

Unknown Diaqua-bis-(4-carb-oxy-2-propyl-1H-imidazole-5-carboxyl-ato-?N,O)cobalt(II) N,N-dimethyl-formamide disolvate.
| S-EPMC3009030 | biostudies-literature
Unknown Diaqua-bis-(4-carb-oxy-2-ethyl-1H-imidazole-5-carboxyl-ato-?N,O)zinc N,N-dimethyl-formamide disolvate.
| S-EPMC3089267 | biostudies-literature
Unknown Diaqua-bis-(5-carb-oxy-2-propyl-1H-imidazole-4-carboxyl-ato-?N,O)cadmium N,N-dimethyl-formamide disolvate.
| S-EPMC3238758 | biostudies-literature
Unknown Diaqua-bis(5-carb-oxy-2-propyl-1H-imidazole-4-carboxyl-ato-?N,O)manganese(II) N,N-dimethyl-formamide disolvate.
| S-EPMC2980198 | biostudies-literature
Unknown Diaqua-bis-(4-carb-oxy-2-propyl-1H-imidazole-5-carboxyl-ato-?N,O)copper(II) N,N-dimethyl-formamide disolvate.
| S-EPMC3007369 | biostudies-literature
Unknown Diaqua-bis(5-carb-oxy-2-propyl-1H-imidazole-4-carboxyl-ato-?N,O)nickel(II) N,N-dimethyl-formamide disolvate.
| S-EPMC2983735 | biostudies-literature
Unknown Diaqua-bis-(4-carb-oxy-2-ethyl-1H-imidazole-5-carboxyl-ato-κN,O)manganese(II) N,N-dimethyl-formamide disolvate.
| S-EPMC3151971 | biostudies-literature
Unknown Diaqua-bis-(4-carb-oxy-2-propyl-1H-imidazole-5-carboxyl-ato-κN,O)zinc(II) N,N-dimethyl-formamide disolvate.
| S-EPMC3006990 | biostudies-literature
Unknown Diaqua-bis-(5-carb-oxy-2-propyl-1H-imidazole-4-carboxyl-ato-?N,O)cobalt(II) 3.5-hydrate.
| S-EPMC3050148 | biostudies-literature
Unknown trans-Diaqua-bis-[5-carb-oxy-2-(3-pyrid-yl)-1H-imidazole-4-carboxyl-ato-κN,O]cobalt(II).
| S-EPMC3200953 | biostudies-literature