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4-[(2E)-2-(2-Hy-droxy-benzyl-idene)hydrazin-1-yl]benzonitrile.

ABSTRACT: The asymmetric unit of the title Schiff base, C(14)H(11)N(3)O, contains two independent mol-ecules which have similar conformations. The dihedral angles between the benzene rings are 4.19?(9) and 14.18?(9)° in the two mol-ecules. An intra-molecular O-H?N hydrogen bond stabilizes the mol-ecular conformation of each mol-ecules. The crystal packing is dominated by pairs of equivalent N-H?N and C-H?O hydrogen bonds which arrange the mol-ecules into layers parallel to (-111).

SUBMITTER: Mohamed SK

PROVIDER: S-EPMC3470239 | biostudies-literature | 2012 Oct

REPOSITORIES: biostudies-literature

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4-[(2E)-2-(2-Hy-droxy-benzyl-idene)hydrazin-1-yl]benzonitrile.

Mohamed Shaaban K SK Bogdanović Goran A GA Abdelhamid Antar A AA Novaković Sladjana B SB Potgeiter Herman H

Acta crystallographica. Section E, Structure reports online 20120908 Pt 10

The asymmetric unit of the title Schiff base, C(14)H(11)N(3)O, contains two independent mol-ecules which have similar conformations. The dihedral angles between the benzene rings are 4.19 (9) and 14.18 (9)° in the two mol-ecules. An intra-molecular O-H⋯N hydrogen bond stabilizes the mol-ecular conformation of each mol-ecules. The crystal packing is dominated by pairs of equivalent N-H⋯N and C-H⋯O hydrogen bonds which arrange the mol-ecules into layers parallel to (-111). ...[more]

PMID: 23125683

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