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Diphenyl (methyl-amido)-phosphate.


ABSTRACT: The N-H bond in the title compound, C(13)H(14)NO(3)P, is syn-oriented relative to the P=O bond. The N atom deviates somewhat from planarity, the sum of the bond angles being 353.3°. The P atom has a distorted tetra-hedral coordination; its bond angles are in the range 93.96?(5)-116.83?(6)°. In the crystal, mol-ecules form centrosymmetric dimers through P=O?H-N hydrogen bonds.

SUBMITTER: Sabbaghi F 

PROVIDER: S-EPMC3470308 | biostudies-literature | 2012 Oct

REPOSITORIES: biostudies-literature

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Diphenyl (methyl-amido)-phosphate.

Sabbaghi Fahimeh F   Pourayoubi Mehrdad M   Nečas Marek M   Bartoš Peter P  

Acta crystallographica. Section E, Structure reports online 20120915 Pt 10


The N-H bond in the title compound, C(13)H(14)NO(3)P, is syn-oriented relative to the P=O bond. The N atom deviates somewhat from planarity, the sum of the bond angles being 353.3°. The P atom has a distorted tetra-hedral coordination; its bond angles are in the range 93.96 (5)-116.83 (6)°. In the crystal, mol-ecules form centrosymmetric dimers through P=O⋯H-N hydrogen bonds. ...[more]

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