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Diphenyl (benzyl-amido)phosphate.

ABSTRACT: The title compound, C(19)H(18)NO(3)P, was prepared by the reaction of diphenyl phospho-rochloridate and benzyl-amine. In the crystal structure, mol-ecules are linked via N-H⋯O=P hydrogen bonds into extended chains parallel to the c axis.

SUBMITTER: Pourayoubi M

PROVIDER: S-EPMC2980091 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Diphenyl (2-chloro-benzyl-amido)-phosphate.

Project description:In the title compound, C(19)H(17)ClNO(3)P, the P atom exhibits a distorted tetra-hedral configuration. In the crystal, pairs of inter-molecular N-H?O(P) hydrogen bonds form centrosymmetric dimers.

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Project description:The N-H bond in the title compound, C(13)H(14)NO(3)P, is syn-oriented relative to the P=O bond. The N atom deviates somewhat from planarity, the sum of the bond angles being 353.3°. The P atom has a distorted tetra-hedral coordination; its bond angles are in the range 93.96?(5)-116.83?(6)°. In the crystal, mol-ecules form centrosymmetric dimers through P=O?H-N hydrogen bonds.

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Diphenyl (isopropyl-amido)-phosphate.

Project description:The P atom in the title compound, C15H18NO3P, is in a distorted tetra-hedral P(O)(O)2N environment; the bond angles at P are in the range 98.16?(6)-115.82?(6)°. In the crystal, adjacent mol-ecules are linked via N-H?O=P hydrogen bonds into a chain running parallel to the b axis. The methyl groups are disordered over two sets of sites in a 0.677?(14):0.323?(14) ratio. The crystal studied was a non-merohedral twin with a refined minor component of 22.31?(4)%.

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Project description:The P atom in the title compound, C(19)H(18)NO(3)P, exhibits a distorted tetra-hedral configuration while the N atom shows a planar coordination. In the crystal, inter-molecular N-H?O hydrogen bonds form centrosymmetric dimers.

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Diphenyl (cyclo-pentyl-amido)-phospho-nate.

Project description:In the title mol-ecule, C(17)H(20)NO(3)P, the P atom is bonded in a distorted tetra-hedral environment. The dihedral angle between the two phenyl rings is 23.52?(10)°. The phosphoryl and N-H groups are anti with respect to one another. The -CH(2)-CH(2)-CH(2)-CH(2)- sequence of atoms in the cyclo-pentyl ring is disordered over two sets of sites with refined occupancies of 0.574?(10) and 0.426?(10). In the crystal, mol-ecules are linked via N-H?O=P hydrogen bonds to form extended chains along [010].

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Diphenyl (o-tolyl-amido)-phospho-nate.

Project description:The asymmetric unit of the title compound, C(19)H(18)NO(3)P, contains two independent mol-ecules in which the P atoms are found in slightly distorted tetrahedral environments. In the crystal, pairs of inter-molecular N-H?O(P) hydrogen bonds form two independent centrosymmetric dimers.

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(Cobaltoceniumyl-amido)-pyridinium hexa-fluorido-phosphate.

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O,O'-Dimethyl (cyclo-hexyl-amido)-thio-phosphate.

Project description:The P atom in the title compound, C(8)H(18)NO(2)PS, is bonded in a distorted tetra-hedral PSO(2)N environment with bond angles in the range of 99.23?(5)-115.17?(4)°. The cyclo-hexane ring is disordered over two sets of sites with refined occupancies of 0.528?(5) and 0.472?(5). The ring in both disorder components adopts a chair conformation with the N-H group oriented equatorially. In the crystal, pairs of P=S?H-N hydrogen bonds form inversion dimers.

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