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4-Dimethyl-amino-N'-(2-hy-droxy-4-meth-oxy-benzyl-idene)benzohydrazide methanol monosolvate.

ABSTRACT: The asymmetric unit of the title compound, C(17)H(19)N(3)O(3)·CH(4)O, comprises two Schiff base mol-ecules and two methanol solvent mol-ecules. The Schiff base mol-ecules are approximately planar, with r.m.s. deviations from the planes defined by the non-H atoms of 0.107 and 0.154?Å, and with dihedral angles between the benzene rings of 4.49?(15) and 8.39?(15)°, respectively. This near-planarity is assisted by the formation of intra-molecular O-H?N hydrogen bonds in each mol-ecule. In the crystal, the components are linked by N-H?O and O-H?O hydrogen bonds to form chains along [010].

SUBMITTER: Sun J

PROVIDER: S-EPMC3470357 | biostudies-literature | 2012 Oct

REPOSITORIES: biostudies-literature

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4-Dimethyl-amino-N'-(2-hy-droxy-4-meth-oxy-benzyl-idene)benzohydrazide methanol monosolvate.

Sun Jingya J

Acta crystallographica. Section E, Structure reports online 20120926 Pt 10

The asymmetric unit of the title compound, C(17)H(19)N(3)O(3)·CH(4)O, comprises two Schiff base mol-ecules and two methanol solvent mol-ecules. The Schiff base mol-ecules are approximately planar, with r.m.s. deviations from the planes defined by the non-H atoms of 0.107 and 0.154 Å, and with dihedral angles between the benzene rings of 4.49 (15) and 8.39 (15)°, respectively. This near-planarity is assisted by the formation of intra-molecular O-H⋯N hydrogen bonds in each mol-ecule. In the crysta ...[more]

PMID: 23125770

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