(2E)-2-{[3-Methyl-5-(2-naphth-yloxy)-1-phenyl-1H-pyrazol-4-yl]methyl-idene}hydrazinecarbothio-amide monohydrate.

ABSTRACT: In the title compound, C(22)H(19)N(5)OS·H(2)O, the naphthalene ring system and the benzene ring [dihedral angle = 85.19?(8)°] make dihedral angles of 87.02?(9) and 14.41?(10)°, respectively, with the pyrazole ring. The mean plane through the 2-methyl-enehydrazinecarbothio-amide group [C-N-N-C(=S)-N; maximum deviation = 0.022?(1)?Å] is slightly twisted from the pyrazole ring [dihedral angle = 5.60?(11)°]. In the crystal, mol-ecules are linked by N-H?S, N-H?O, O-H?S, O-H?N and C-H?S hydrogen bonds into sheets parallel to the ab plane. ?-? inter-actions are also observed [centroid-to-centroid distances = 3.7778?(12) and 3.7010?(12)?Å].

SUBMITTER: Fun HK 

PROVIDER: S-EPMC3470403 | biostudies-literature | 2012 Oct

REPOSITORIES: biostudies-literature