Supramolecular hydrogels formed from poly(viologen) cross-linked with cyclodextrin dimers and their physical properties.

ABSTRACT: Supramolecular materials with noncovalent bonds have attracted much attention due to their exclusive properties differentiating them from materials formed solely by covalent bonds. Especially interesting are rotor molecules of topological complexes that shuttle along a polymer chain. The shuttling of these molecules should greatly improve the tension strength. Our research employs cyclodextrin (CD) as a host molecule, because CD effectively forms polyrotaxanes with polymers. Herein we report the formation of supramolecular hydrogels with an α-CD dimer (α,α-CD dimer) as a topological linker molecule, and a viologen polymer (VP) as the polymer chain. The supramolecular hydrogel of α,α-CD dimer/VP forms a self-standing gel, which does not relax (G' > G'') in the frequency range 0.01-10 rad·s(

SUBMITTER: Takashima Y 

PROVIDER: S-EPMC3510991 | biostudies-literature | 2012

REPOSITORIES: biostudies-literature