Ontology highlight
ABSTRACT:
SUBMITTER: Martin AR
PROVIDER: S-EPMC3510996 | biostudies-literature | 2012
REPOSITORIES: biostudies-literature
Martin Anthony R AR Chartoire Anthony A Slawin Alexandra M Z AM Nolan Steven P SP
Beilstein journal of organic chemistry 20120927
The use of [Pd(NHC)(cinnamyl)Cl] precatalysts in the direct arylation of heterocycles has been investigated. Among four different precatalysts, [Pd(SIPr)(cinnamyl)Cl] proved to be the most efficient promoter of the reaction. The C-H functionalization of sulfur- or nitrogen-containing heterocycles has been achieved at low catalyst loadings. These catalyst charges range from 0.1 to 0.01 mol % palladium. ...[more]