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ABSTRACT:
SUBMITTER: Goswami LN
PROVIDER: S-EPMC3528802 | biostudies-literature | 2012 Dec
REPOSITORIES: biostudies-literature
Goswami Lalit N LN Houston Zachary H ZH Sarma Saurav J SJ Li Hairong H Jalisatgi Satish S SS Hawthorne M Frederick MF
The Journal of organic chemistry 20121129 24
We report methods for the synthesis of vertex-differentiated icosahedral closo-boranes. A single B-OH vertex of the icosahedral borane [closo-B(12)(OH)(12)](2-) was derivatized to prepare [closo-B(12)(OR)(OH)(11)](2-) using optimized alkylation conditions and purification procedures. Several representative vertex-differentiated icosahedral closo-boranes were prepared utilizing carbonate ester and azide-alkyne click chemistries on the surface of the closo-B(12)(2-) core. ...[more]