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Air-stable, highly fluorescent primary phosphanes.

ABSTRACT: Light without fright: a synthetic route to fluorescent primary phosphanes (RPH(2)) that are resistant to air oxidation both in the solid state and in chloroform solution is described. These versatile precursors undergo hydrophosphination to give tripodal ligands and subsequently fluorescent transition-metal complexes.

SUBMITTER: Davies LH 

PROVIDER: S-EPMC3531623 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature

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Air-stable, highly fluorescent primary phosphanes.

Davies Laura H LH   Stewart Beverly B   Harrington Ross W RW   Clegg William W   Higham Lee J LJ  

Angewandte Chemie (International ed. in English) 20120319 20

Light without fright: a synthetic route to fluorescent primary phosphanes (RPH(2)) that are resistant to air oxidation both in the solid state and in chloroform solution is described. These versatile precursors undergo hydrophosphination to give tripodal ligands and subsequently fluorescent transition-metal complexes. ...[more]

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