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Functionally Diverse Nylon-3 Copolymers from Readily Accessible ?-Lactams.

ABSTRACT: A new family of ?-lactams is described that enables anionic ring-opening polymerization (AROP) to prepare nylon-3 materials bearing diverse appended functionality, including carboxylic acid, thiol, hydroxyl and secondary amine groups. Nylon-3 copolymers generated with the new ?-lactams are shown to display distinctive self-assembly behavior and biological properties.

SUBMITTER: Zhang J 

PROVIDER: S-EPMC3551626 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

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Functionally Diverse Nylon-3 Copolymers from Readily Accessible β-Lactams.

Zhang Jihua J   Markiewicz Matthew J MJ   Weisblum Bernard B   Stahl Shannon S SS   Gellman Samuel H SH  

ACS macro letters 20120523 6

A new family of β-lactams is described that enables anionic ring-opening polymerization (AROP) to prepare nylon-3 materials bearing diverse appended functionality, including carboxylic acid, thiol, hydroxyl and secondary amine groups. Nylon-3 copolymers generated with the new β-lactams are shown to display distinctive self-assembly behavior and biological properties. ...[more]

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