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Methyl 2,4-dihy-droxy-5-(2-methyl-propanamido)-benzoate.

ABSTRACT: In the title compound, C(12)H(15)NO(5), the dihedral angle between the benzene ring and the C atoms of the terminal isopropyl group is 83.48?(16)°. Intra-molecular N-H?O and O-H?O hydrogen bonds generate S(5) and S(6) rings, respectively. In the crystal, mol-ecules are linked by O-H?O hydrogen bonds, generating C(7) chains propagating in [001]. Weak aromatic ?-? stacking [centroid-centroid separation = 3.604?(3)?Å] is also observed.

SUBMITTER: Naz SS

PROVIDER: S-EPMC3569756 | biostudies-literature | 2013 Feb

REPOSITORIES: biostudies-literature

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Methyl 2,4-dihy-droxy-5-(2-methyl-propanamido)-benzoate.

Naz Syeda Sohaila SS Islam Nazar Ul NU Tahir M Nawaz MN Shah Muhammad Raza MR

Acta crystallographica. Section E, Structure reports online 20130112 Pt 2

In the title compound, C(12)H(15)NO(5), the dihedral angle between the benzene ring and the C atoms of the terminal isopropyl group is 83.48 (16)°. Intra-molecular N-H⋯O and O-H⋯O hydrogen bonds generate S(5) and S(6) rings, respectively. In the crystal, mol-ecules are linked by O-H⋯O hydrogen bonds, generating C(7) chains propagating in [001]. Weak aromatic π-π stacking [centroid-centroid separation = 3.604 (3) Å] is also observed. ...[more]

PMID: 23424502

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