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Dimethyl 2-[(acridin-9-yl)methyl-idene]malonate.


ABSTRACT: In the title compound, C(19)H(15)NO(4), the acridine system is essentially planar (r.m.s. deviation = 0.015?Å). The crystal packing exhibits ?-? inter-actions between pairs of centrosymmetric mol-ecules, one of them between the central heterocyclic rings and others between the outer benzene rings of the acridine systems, with centroid-centroid distances of 3.692?(1) and 3.754?(1)?Å, respectively. These pairs are further linked by additional ?-? inter-actions along the a-axis direction through one of the two outer benzene ring of neighboring mol-ecules, with a centroid-centroid distance of 3.642?(2)?Å.

SUBMITTER: de Almeida SM 

PROVIDER: S-EPMC3569759 | biostudies-literature | 2013 Feb

REPOSITORIES: biostudies-literature

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Dimethyl 2-[(acridin-9-yl)methyl-idene]malonate.

de Almeida Sinara M V SM   Pitta Ivan R IR   de Lima Maria do Carmo A Mdo C   Mendonça Junior Francisco J B FJ   de Simone Carlos A CA  

Acta crystallographica. Section E, Structure reports online 20130112 Pt 2


In the title compound, C(19)H(15)NO(4), the acridine system is essentially planar (r.m.s. deviation = 0.015 Å). The crystal packing exhibits π-π inter-actions between pairs of centrosymmetric mol-ecules, one of them between the central heterocyclic rings and others between the outer benzene rings of the acridine systems, with centroid-centroid distances of 3.692 (1) and 3.754 (1) Å, respectively. These pairs are further linked by additional π-π inter-actions along the a-axis direction through on  ...[more]

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