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Electronic effects in iridium C-H borylations: insights from unencumbered substrates and variation of boryl ligand substituents.


ABSTRACT: Experiment and theory favour a model of C-H borylation where significant proton transfer character exists in the transition state.

SUBMITTER: Vanchura BA 

PROVIDER: S-EPMC3573526 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

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Electronic effects in iridium C-H borylations: insights from unencumbered substrates and variation of boryl ligand substituents.

Vanchura Britt A BA   Preshlock Sean M SM   Roosen Philipp C PC   Kallepalli Venkata A VA   Staples Richard J RJ   Maleczka Robert E RE   Singleton Daniel A DA   Smith Milton R MR  

Chemical communications (Cambridge, England) 20100920 41


Experiment and theory favour a model of C-H borylation where significant proton transfer character exists in the transition state. ...[more]

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