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Electronic effects in iridium C-H borylations: insights from unencumbered substrates and variation of boryl ligand substituents.

ABSTRACT: Experiment and theory favour a model of C-H borylation where significant proton transfer character exists in the transition state.

SUBMITTER: Vanchura BA

PROVIDER: S-EPMC3573526 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

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Electronic effects in iridium C-H borylations: insights from unencumbered substrates and variation of boryl ligand substituents.

Vanchura Britt A BA Preshlock Sean M SM Roosen Philipp C PC Kallepalli Venkata A VA Staples Richard J RJ Maleczka Robert E RE Singleton Daniel A DA Smith Milton R MR

Chemical communications (Cambridge, England) 20100920 41

Experiment and theory favour a model of C-H borylation where significant proton transfer character exists in the transition state. ...[more]

PMID: 20852803

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