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Triphenyl(3,4,5-trimethoxy-benzyl)-phospho-nium chloride monohydrate.

ABSTRACT: The asymmetric unit of the title salt, C(28)H(28)O(3)P(+)·Cl(-)·H(2)O, contains a benzyl-triphenyl-phospho-nium cation, a chloride counter-ion, and a water mol-ecule of crystallization. The 3,4,5-trimeth-oxy substituents of the benzylic functionality are arranged with the 3,5-methyl groups lying approximately in the aromatic ring plane while the 4-methyl group is out of the plane.

SUBMITTER: Barkell AM

PROVIDER: S-EPMC2959282 | biostudies-literature | 2008 Sep

REPOSITORIES: biostudies-literature

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Triphenyl(3,4,5-trimethoxy-benzyl)-phospho-nium chloride monohydrate.

Barkell Alice M AM Sharp Jonathan J Simpson Stephen J SJ

Acta crystallographica. Section E, Structure reports online 20080906 Pt 10

The asymmetric unit of the title salt, C(28)H(28)O(3)P(+)·Cl(-)·H(2)O, contains a benzyl-triphenyl-phospho-nium cation, a chloride counter-ion, and a water mol-ecule of crystallization. The 3,4,5-trimeth-oxy substituents of the benzylic functionality are arranged with the 3,5-methyl groups lying approximately in the aromatic ring plane while the 4-methyl group is out of the plane. ...[more]

PMID: 21201090

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