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Diaqua-bis-[4-(1H-imidazol-2-yl)pyridine-?N]bis-(nitrato-?O)cadmium.

ABSTRACT: In the title compound, [Cd(NO3)2(C8H7N3)2(H2O)2], the Cd(II) cation is situated on an inversion center and is coordinated by the O atoms of two nitrate anions, by the N atoms of two 4-(imidazol-2-yl)pyridine ligands and by two water O atoms in a slightly distorted N2O4 octa-hedral geometry. The dihedral angle between the imidazole and pyridine rings is 1.6?(2)°. In the crystal, mol-ecules are linked by N-H?O, O-H?N and O-H?O hydrogen bonds, forming a three-dimensional network.

SUBMITTER: Zhang CY

PROVIDER: S-EPMC3588280 | biostudies-literature | 2013 Jan

REPOSITORIES: biostudies-literature

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Diaqua-bis-[4-(1H-imidazol-2-yl)pyridine-κN]bis-(nitrato-κO)cadmium.

Zhang Chuan-Yue CY Wang Tao T Jin Chuan-Ming CM

Acta crystallographica. Section E, Structure reports online 20121222 Pt 1

In the title compound, [Cd(NO3)2(C8H7N3)2(H2O)2], the Cd(II) cation is situated on an inversion center and is coordinated by the O atoms of two nitrate anions, by the N atoms of two 4-(imidazol-2-yl)pyridine ligands and by two water O atoms in a slightly distorted N2O4 octa-hedral geometry. The dihedral angle between the imidazole and pyridine rings is 1.6 (2)°. In the crystal, mol-ecules are linked by N-H⋯O, O-H⋯N and O-H⋯O hydrogen bonds, forming a three-dimensional network. ...[more]

PMID: 23476357

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[Aqua-bis-(nitrato-κO)copper(II)]-μ-{bis-[5-methyl-3-(pyridin-2-yl)-1H-pyrazol-4-yl]selenide}-[diaqua-(nitrato-κO)copper(II)] nitrate monohydrate.

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