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Diaqua-bis-(nitrato-?O)bis-(pyridine-?N)manganese(II).

ABSTRACT: The structure of the title manganese complex, [Mn(NO3)2(C5H5N)2(H2O)2], consists of discrete monomeric entities with Mn(2+) ions located on centres of inversion. The metal cation is octahedrally coordinated by a trans-N2O4 donor set with the pyridine N atoms located in the apical positions. Discrete mol-ecules are linked by O-H?O hydrogen bonds into one-dimensional supra-molecular infinite chains along the b and c axes.

SUBMITTER: Alam N

PROVIDER: S-EPMC3588364 | biostudies-literature | 2013 Jan

REPOSITORIES: biostudies-literature

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Diaqua-bis-(nitrato-κO)bis-(pyridine-κN)manganese(II).

Alam Naveed N Shahid Muhammad M Rauf M Khawar MK

Acta crystallographica. Section E, Structure reports online 20121205 Pt 1

The structure of the title manganese complex, [Mn(NO3)2(C5H5N)2(H2O)2], consists of discrete monomeric entities with Mn(2+) ions located on centres of inversion. The metal cation is octahedrally coordinated by a trans-N2O4 donor set with the pyridine N atoms located in the apical positions. Discrete mol-ecules are linked by O-H⋯O hydrogen bonds into one-dimensional supra-molecular infinite chains along the b and c axes. ...[more]

PMID: 23476361

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