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[?-N (1),N (2)-Bis(pyridin-2-yl)hydrazine-1,2-dicarbothio-amidato]bis-[chlorido-copper(II)].

ABSTRACT: The binuclear title compound, [Cu2(C12H10N6S2)Cl2], possesses twofold rotational symmetry. The Cu(II) atom occupies a four-coordinate pseudo-tetra-hedral environment bound to one S atom, one imine N atom and one pyridine N atom from the N(1),N(2)-bis-(pyridin-2-yl)hydrazine-1,2-dicarbo-thio-amidate ligand, and one Cl(-) anion. The metal atoms are connected via the bis-tridentate ligand into a binuclear structure. The mol-ecule is bow-shaped with the pyridine rings inclined to one another by 51.56?(14)°. In the crystal, N-H?Cl hydrogen bonds lead to the formation of ribbons propagating along [001]. These ribbons are connected via C-H?Cl, C-H?S and ?-? inter-actions [centroid-centroid distance = 3.6146?(19)?Å], leading to the formation of a three-dimensional structure.

SUBMITTER: Liu Y

PROVIDER: S-EPMC3588330 | biostudies-literature | 2013 Jan

REPOSITORIES: biostudies-literature

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[μ-N (1),N (2)-Bis(pyridin-2-yl)hydrazine-1,2-dicarbothio-amidato]bis-[chlorido-copper(II)].

Liu Yang Y Zhang Bingguang B Deng Kejian K

Acta crystallographica. Section E, Structure reports online 20121212 Pt 1

The binuclear title compound, [Cu2(C12H10N6S2)Cl2], possesses twofold rotational symmetry. The Cu(II) atom occupies a four-coordinate pseudo-tetra-hedral environment bound to one S atom, one imine N atom and one pyridine N atom from the N(1),N(2)-bis-(pyridin-2-yl)hydrazine-1,2-dicarbo-thio-amidate ligand, and one Cl(-) anion. The metal atoms are connected via the bis-tridentate ligand into a binuclear structure. The mol-ecule is bow-shaped with the pyridine rings inclined to one another by 51.5 ...[more]

PMID: 23476341

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