Unknown

Dataset Information

0

Catena-Poly[[(triphenyl-phosphane)copper(I)]-di-?-iodido-[(triphenyl-phosphane)copper(I)]-?-{1,2-bis-[1-(pyridin-4-yl)ethyl-idene]hydrazine}].

ABSTRACT: In the title coordination polymer, [Cu(2)I(2)(C(14)H(14)N(4))(C(18)H(15)P)(2)](n), the Cu(I) atom is coordinated by two I atoms, one P atom and one N atom in a fairly regular tetra-hedral arrangement. A crystallographic inversion centre generates a Cu(2)I(2) diamond with a Cu-Cu separation of 3.0120?(5)?Å. The complete N,N'-(1-pyridin-4-yl-ethethyl-idene)-hydrazine mol-ecule is also generated by inversion symmetry, and this bridging ligand leads to [011] polymeric chains in the crystal structure.

SUBMITTER: Fun HK 

PROVIDER: S-EPMC3201507 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

catena-Poly[[(triphenyl-phosphane)copper(I)]-di-μ-iodido-[(triphenyl-phosphane)copper(I)]-μ-{1,2-bis-[1-(pyridin-4-yl)ethyl-idene]hydrazine}].

Fun Hoong-Kun HK   Loh Wan-Sin WS   Patra Goutam K GK   Mukherjee Anindita A   Pal Pankaj K PK  

Acta crystallographica. Section E, Structure reports online 20110914 Pt 10

In the title coordination polymer, [Cu(2)I(2)(C(14)H(14)N(4))(C(18)H(15)P)(2)](n), the Cu(I) atom is coordinated by two I atoms, one P atom and one N atom in a fairly regular tetra-hedral arrangement. A crystallographic inversion centre generates a Cu(2)I(2) diamond with a Cu-Cu separation of 3.0120 (5) Å. The complete N,N'-(1-pyridin-4-yl-ethethyl-idene)-hydrazine mol-ecule is also generated by inversion symmetry, and this bridging ligand leads to [011] polymeric chains in the crystal structure  ...[more]

Similar Datasets

Unknown [4-Bromo-N-(pyridin-2-yl-methyl-idene)aniline-?(2)N,N']iodido(triphenyl-phosphane-?P)copper(I).
| S-EPMC3393242 | biostudies-literature
Unknown catena-Poly[[[(triphenyl-phosphane)copper(I)]-di-μ-iodido-[(triphenyl-phosphane)copper(I)]-μ-[3,6-bis-(4-pyrid-yl)-1,2,4,5-tetra-zine]] acetonitrile disolvate].
| S-EPMC3008982 | biostudies-literature
Unknown catena-Poly[[(nitrito-?O,O')silver(I)]-?-1,2-bis-[1-(pyridin-4-yl)ethyl-idene]hydrazine-?N:N'].
| S-EPMC3212196 | biostudies-literature
Unknown catena-Poly[[(triphenyl-phosphane-?P)copper(I)]-di-?-bromido-[(triphenyl-phos-phane-?P)copper(I)]-?-1,3-bis(pyridin-4-yl)-propane-?N:N'].
| S-EPMC3297220 | biostudies-literature
Unknown Bis{μ-(E)-methyl 4-[(2-carbamothio-ylhydrazinyl-idene)meth-yl]benzoate-κS:S}bis-[iodido(triphenyl-phosphane-κP)copper(I)].
| S-EPMC3246960 | biostudies-literature
Unknown Iodido[1-(propan-2-yl-idene)thio-semi-carbazide-?S]bis-(triphenyl-phosphane-?P)copper(I).
| S-EPMC3515154 | biostudies-other
Unknown Iodido[5-methyl-1H-benzimidazole-2(3H)-thione-?S]bis-(triphenyl-phosphane-?P)copper(I) methanol monosolvate.
| S-EPMC3470167 | biostudies-literature
Unknown (1E,2E)-1,2-Bis[1-(3-nitro-phen-yl)ethyl-idene]hydrazine.
| S-EPMC3295435 | biostudies-literature
Unknown (E,E)-1,2-Bis[1-(2-bromo-phen-yl)ethyl-idene]hydrazine.
| S-EPMC3007455 | biostudies-literature
Unknown (1E,2E)-1,2-Bis[1-(3-chloro-phen-yl)ethyl-idene]hydrazine.
| S-EPMC3239059 | biostudies-literature