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Catena-Poly[[(triphenyl-phosphane)copper(I)]-di-?-iodido-[(triphenyl-phosphane)copper(I)]-?-{1,2-bis-[1-(pyridin-4-yl)ethyl-idene]hydrazine}].

ABSTRACT: In the title coordination polymer, [Cu(2)I(2)(C(14)H(14)N(4))(C(18)H(15)P)(2)](n), the Cu(I) atom is coordinated by two I atoms, one P atom and one N atom in a fairly regular tetra-hedral arrangement. A crystallographic inversion centre generates a Cu(2)I(2) diamond with a Cu-Cu separation of 3.0120?(5)?Å. The complete N,N'-(1-pyridin-4-yl-ethethyl-idene)-hydrazine mol-ecule is also generated by inversion symmetry, and this bridging ligand leads to [011] polymeric chains in the crystal structure.

SUBMITTER: Fun HK

PROVIDER: S-EPMC3201507 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

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catena-Poly[[(triphenyl-phosphane)copper(I)]-di-μ-iodido-[(triphenyl-phosphane)copper(I)]-μ-{1,2-bis-[1-(pyridin-4-yl)ethyl-idene]hydrazine}].

Fun Hoong-Kun HK Loh Wan-Sin WS Patra Goutam K GK Mukherjee Anindita A Pal Pankaj K PK

Acta crystallographica. Section E, Structure reports online 20110914 Pt 10

In the title coordination polymer, [Cu(2)I(2)(C(14)H(14)N(4))(C(18)H(15)P)(2)](n), the Cu(I) atom is coordinated by two I atoms, one P atom and one N atom in a fairly regular tetra-hedral arrangement. A crystallographic inversion centre generates a Cu(2)I(2) diamond with a Cu-Cu separation of 3.0120 (5) Å. The complete N,N'-(1-pyridin-4-yl-ethethyl-idene)-hydrazine mol-ecule is also generated by inversion symmetry, and this bridging ligand leads to [011] polymeric chains in the crystal structure ...[more]

PMID: 22058699

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