Unknown

Dataset Information

0

3,3'-(1-Oxopropane-1,3-di-yl)bis-(1,3-thia-zolidine-2-thione) chloro-benzene hemisolvate.

ABSTRACT: The title compound, C9H12N2OS4·0.5C6H5Cl, which contains two 1,3-thia-zolidine-2-thione rings, is a by-product of the synthesis of 3-acryloyl-1,3-thia-zolidine-2-thione. The dihedral angle between these rings is 79.95?(9)°, with both rings displaying a twisted conformation. The twist angle of the amide group is 5.6?(1)°. In the crystal, the molecules are linked into [001] chains by C-H?O interactions. The chloro-benzene solvent mol-ecule was found to show unresolvable disorder about a centre of inversion and its contribution to the scattering was removed with the SQUEEZE option in PLATON [Spek (2009 ?). Acta Cryst. D65, 148-155].

SUBMITTER: Franzel C 

PROVIDER: S-EPMC3588431 | biostudies-literature | 2013 Mar

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

3,3'-(1-Oxopropane-1,3-di-yl)bis-(1,3-thia-zolidine-2-thione) chloro-benzene hemisolvate.

Franzel Christine C   Purdy Andrew A   Butcher Ray J RJ  

Acta crystallographica. Section E, Structure reports online 20130213 Pt 3

The title compound, C9H12N2OS4·0.5C6H5Cl, which contains two 1,3-thia-zolidine-2-thione rings, is a by-product of the synthesis of 3-acryloyl-1,3-thia-zolidine-2-thione. The dihedral angle between these rings is 79.95 (9)°, with both rings displaying a twisted conformation. The twist angle of the amide group is 5.6 (1)°. In the crystal, the molecules are linked into [001] chains by C-H⋯O interactions. The chloro-benzene solvent mol-ecule was found to show unresolvable disorder about a centre of  ...[more]

Similar Datasets

Unknown Crystal structure of [3-(4,5-di-hydro-1,3-thia-zolin-2-yl-?N)-1,3-thia-zolidine-2-thione-?S (2)](1,3-thia-zol-idine-2-thione-?S (2))copper(I) nitrate.
| S-EPMC4158518 | biostudies-other
Unknown 1,3-Bis(chloro-meth-yl)benzene.
| S-EPMC3770413 | biostudies-literature
Unknown 3-[1-(4-Chloro-phen-yl)eth-yl]-1,3-thia-zinane-2-thione.
| S-EPMC3051552 | biostudies-literature
Unknown 1,3-Bis[(3-chloro-pyrazin-2-yl)-oxy]benzene.
| S-EPMC3648331 | biostudies-literature
Unknown trans-5-(4-Chloro-phen-yl)-N-cyclo-hexyl-4-methyl-2-oxo-1,3-thia-zolidine-3-carboxamide.
| S-EPMC2961588 | biostudies-literature
Unknown 1,3-Bis(chloro-meth-yl)-2-methyl-5-nitro-benzene.
| S-EPMC2960992 | biostudies-literature
Unknown 3,3'-(Ethane-1,2-di-yl)bis-(3,4-dihydro-2H-1,3-benzoxazine).
| S-EPMC3254492 | biostudies-literature
Unknown 3-(tert-But-oxy-carbon-yl)-2-(4-chloro-phen-yl)-1,3-thia-zolidine-4-carb-oxy-lic acid.
| S-EPMC2983415 | biostudies-literature
Unknown 1,4-Bis(4-chloro-phenyl-seleno)-2,5-di-methoxy-benzene.
| S-EPMC2967934 | biostudies-literature
Unknown (Z)-5-(4-Fluoro-benzyl-idene)-1,3-thia-zolidine-2,4-dione.
| S-EPMC2960296 | biostudies-literature