Ontology highlight
ABSTRACT:
SUBMITTER: Maercz M
PROVIDER: S-EPMC3588472 | biostudies-literature | 2013 Mar
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20130216 Pt 3
In the title coordination polymer, [Zr(C8H2O6)(C6H12N2O)2] n , the Zr(IV) atom, which lies on a crystallographic twofold rotation axis, is coordinated by two O,O'-bidentate 2,5-dioxidoterephthalate (DHTP(4-)) ligands and two O-bonded 1,3-dimethyl-1,3-diazinan-2-one (DMPU) ligands (the latter in a cis orientation) in a distorted ZrO6 octa-hedral geometry. The deprotonated hy-droxy and carb-oxy O atoms of the DHTP(4-) ligand chelate the Zr(IV) ion via a six-membered ring; the dihedral angle betwee ...[more]