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Dibromido(6-methyl-2,2'-bipyridine-?(2) N,N')cobalt(II).

ABSTRACT: In the mol-ecule of the title compound, [CoBr2(C11H10N2)], the Co(II) atom is four-coordinated in a distorted tetra-hedral geometry by two N atoms from a chelating 6-methyl-2,2'-bipyridine ligand and two terminal Br atoms. In the crystal, ?-? stacking inter-actions between the pyridine rings along the a-axis direction [centroid-centroid distance = 3.761?(7)?Å] and C-H?Br hydrogen bonds in the bc plane together generate the three-dimensional packing.

SUBMITTER: Shirvan SA

PROVIDER: S-EPMC3588722 | biostudies-literature | 2012 Dec

REPOSITORIES: biostudies-literature

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Dibromido(6-methyl-2,2'-bipyridine-κ(2) N,N')cobalt(II).

Shirvan Sadif A SA Haydari Dezfuli Sara S Khazali Fereydoon F Borsalani Ali A

Acta crystallographica. Section E, Structure reports online 20121107 Pt 12

In the mol-ecule of the title compound, [CoBr2(C11H10N2)], the Co(II) atom is four-coordinated in a distorted tetra-hedral geometry by two N atoms from a chelating 6-methyl-2,2'-bipyridine ligand and two terminal Br atoms. In the crystal, π-π stacking inter-actions between the pyridine rings along the a-axis direction [centroid-centroid distance = 3.761 (7) Å] and C-H⋯Br hydrogen bonds in the bc plane together generate the three-dimensional packing. ...[more]

PMID: 23468687

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