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(Perchlorato-?O)tris-(triphenyl-phosphine-?P)silver(I).

ABSTRACT: In the title complex, [Ag(C(18)H(15)P)(3)(ClO(4))], the silver coord-ination environment is dominated by the distorted P(3)AgO tetra-hedron in which Ag-O = 2.608?(12)?Å and the Ag-P bond lengths are 2.5663?(17), 2.5076(16) and 2.5450?(17)?Å. The perchlorate O-atoms are disordered over two positions in a 0.584?(14):0.416?(14) ratio.

SUBMITTER: Cui LN

PROVIDER: S-EPMC3007391 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

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(Perchlorato-κO)tris-(triphenyl-phosphine-κP)silver(I).

Cui Li-Na LN Hu Ke-Yi KY Jin Qiong-Hua QH Zhang Cun-Lin CL

Acta crystallographica. Section E, Structure reports online 20100703 Pt 8

In the title complex, [Ag(C(18)H(15)P)(3)(ClO(4))], the silver coord-ination environment is dominated by the distorted P(3)AgO tetra-hedron in which Ag-O = 2.608 (12) Å and the Ag-P bond lengths are 2.5663 (17), 2.5076(16) and 2.5450 (17) Å. The perchlorate O-atoms are disordered over two positions in a 0.584 (14):0.416 (14) ratio. ...[more]

PMID: 21588119

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