Bis{?-2-[(pyrimidin-2-yl)amino-meth-yl]phenolato}-?(2) N (1):O;?(2) O:N (1)-bis-({2-[(pyrimidin-2-yl-?N)amino-meth-yl]phenol}silver(I)) dihydrate.

ABSTRACT: The Ag(I) atom in the title centrosymmetric dinuclear compound, [Ag2(C11H10N3O)2(C11H11N3O)2]·2H2O, shows a T-shaped coordination arising from bonding to the N atom of a neutral 2-[(pyrimidin-2-yl)amino-meth-yl]phenol ligand, the N atom of the 2-[(pyrimidin-2-yl)amino-meth-yl]phenolate anion [N-Ag-N = 171.8?(1)°] and the terminal O atom of the other anion [Ag-O = 2.606?(3)?Å]. A pair of 2-[(pyrimidin-2-yl)amino-meth-yl]phenolate anions link the two Ag(I) atoms to form the dinuclear compound. In the crystal, adjacent dinuclear mol-ecules are linked to the lattice water mol-ecules, generating an O-H?O- and N-H?O-connected three-dimensional network. In the crystal, the hy-droxy H atom is disordered over two positions in a 1:1 ratio; one half-occupancy H atom is connected to one hy-droxy group, whereas the other half-occupancy H atom is connected to another hy-droxy group.

SUBMITTER: Gao S 

PROVIDER: S-EPMC3588781 | biostudies-literature | 2012 Dec

REPOSITORIES: biostudies-literature