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(5S,11aS)-5-Hydro-per-oxy-1,5,11,11a-tetra-hydro-[1]benzothieno[3,2-f]indol-izin-3(2H)-one.

ABSTRACT: The absolute configuration of the title compound, C14H13NO3S, was assigned from the synthesis and confirmed by the structure determination. The central six-membered ring of the indolizine moiety adopts an envelope conformation, with the greatest deviation from the mean plane of the ring being 0.661 (2) Å for the bridgehead C atom. The benzothiene ring attached to the indolizine ring system is planar to within 0.008 (2) Å. In the crystal, mol-ecules form chains parallel to the b axis via O-H⋯O hydrogen bonds.

SUBMITTER: Vrabel V

PROVIDER: S-EPMC3588932 | biostudies-literature | 2012 Dec

REPOSITORIES: biostudies-literature

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(5S,11aS)-5-Hydro-per-oxy-1,5,11,11a-tetra-hydro-[1]benzothieno[3,2-f]indol-izin-3(2H)-one.

Vrábel Viktor V Svorc Lubomír L Marchalín Stefan S Safář Peter P

Acta crystallographica. Section E, Structure reports online 20121110 Pt 12

The absolute configuration of the title compound, C14H13NO3S, was assigned from the synthesis and confirmed by the structure determination. The central six-membered ring of the indolizine moiety adopts an envelope conformation, with the greatest deviation from the mean plane of the ring being 0.661 (2) Å for the bridgehead C atom. The benzothiene ring attached to the indolizine ring system is planar to within 0.008 (2) Å. In the crystal, mol-ecules form chains parallel to the b axis via O-H⋯O hy ...[more]

PMID: 23476168

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