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Diaqua-bis-[bis-(pyrazin-2-yl) sulfide-?N (4)]bis-(thio-cyanato-?N)iron(II) monohydrate.

ABSTRACT: In the title compound [Fe(NCS)2(C8H6N4S)2(H2O)2]·H2O, the Fe(II) cation is coordinated by two N-bonded thio-cyanate anions, two N (4)-bonded bis-(pyrazin-2-yl) sulfide ligands and two water mol-ecules in an slightly distorted octa-hedral geometry. The Fe(II) cation is located on a center of inversion and the lattice water mol-ecule on a twofold rotation axis. The thio-cyanate anions, the coordinating water mol-ecules and the sulfide ligands occupy general positions. The complex mol-ecules and lattice water mol-ecules are linked into a three-dimensional network by O-H-N and O-H?O hydrogen bonds.

SUBMITTER: Wohlert S 

PROVIDER: S-EPMC3629478 | biostudies-literature | 2013 Apr

REPOSITORIES: biostudies-literature

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Diaqua-bis-[bis-(pyrazin-2-yl) sulfide-κN (4)]bis-(thio-cyanato-κN)iron(II) monohydrate.

Wöhlert Susanne S   Jess Inke I   Näther Christian C  

Acta crystallographica. Section E, Structure reports online 20130309 Pt 4

In the title compound [Fe(NCS)2(C8H6N4S)2(H2O)2]·H2O, the Fe(II) cation is coordinated by two N-bonded thio-cyanate anions, two N (4)-bonded bis-(pyrazin-2-yl) sulfide ligands and two water mol-ecules in an slightly distorted octa-hedral geometry. The Fe(II) cation is located on a center of inversion and the lattice water mol-ecule on a twofold rotation axis. The thio-cyanate anions, the coordinating water mol-ecules and the sulfide ligands occupy general positions. The complex mol-ecules and la  ...[more]

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