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Diaqua-bis[2-(2-pyridylmeth-oxy)pyrazine-?N]bis-(thio-cyanato-?N)cobalt(II).

ABSTRACT: In the title complex, [Co(NCS)(2)(C(10)H(9)N(3)O)(2)(H(2)O)(2)], the Co(II) ion is located on a crystallographic twofold rotation axis and is in a slightly distorted octa-hedral CoN(4)O(2) coordination environment. The dihedral angle between the pyridine and pyrazine rings is 85.86?(10)°. In the crystal structure, inter-molecular O-H?N and O-H?S hydrogen bonds link complex mol-ecules into a three-dimensional network.

SUBMITTER: Yang ZN 

PROVIDER: S-EPMC2959305 | biostudies-literature | 2008 Sep

REPOSITORIES: biostudies-literature

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Diaqua-bis[2-(2-pyridylmeth-oxy)pyrazine-κN]bis-(thio-cyanato-κN)cobalt(II).

Yang Zhong Nian ZN  

Acta crystallographica. Section E, Structure reports online 20080930 Pt 10

In the title complex, [Co(NCS)(2)(C(10)H(9)N(3)O)(2)(H(2)O)(2)], the Co(II) ion is located on a crystallographic twofold rotation axis and is in a slightly distorted octa-hedral CoN(4)O(2) coordination environment. The dihedral angle between the pyridine and pyrazine rings is 85.86 (10)°. In the crystal structure, inter-molecular O-H⋯N and O-H⋯S hydrogen bonds link complex mol-ecules into a three-dimensional network. ...[more]

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