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2-Benzyl-sulfanyl-N-(1,3-dimethyl-imidazolidin-2-yl-idene)aniline.

ABSTRACT: The mol-ecular structure of the title compound, C18H21N3S, shows a twisted conformation with a dihedral angle of 67.45?(4)° between the aromatic ring planes and an N-C-C-S torsion angle of -5.01?(13)°. The imidazolidine ring and the aniline moiety make a dihedral angle of 56.03?(4)° and the asscociated C-N-C angle is 125.71?(10)°. The guanidine-like C=N double bond is clearly localized, with a bond length of 1.2879?(14)?Å. The C-S-C angle is 102.12?(5)° and the S-C(aromatic) and S-C bond lengths are 1.7643?(11) and 1.8159?(12)?Å.

SUBMITTER: Florke U 

PROVIDER: S-EPMC3629606 | biostudies-literature | 2013 Apr

REPOSITORIES: biostudies-literature

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2-Benzyl-sulfanyl-N-(1,3-dimethyl-imidazolidin-2-yl-idene)aniline.

Flörke Ulrich U   Neuba Adam A   Henkel Gerald G  

Acta crystallographica. Section E, Structure reports online 20130320 Pt 4

The mol-ecular structure of the title compound, C18H21N3S, shows a twisted conformation with a dihedral angle of 67.45 (4)° between the aromatic ring planes and an N-C-C-S torsion angle of -5.01 (13)°. The imidazolidine ring and the aniline moiety make a dihedral angle of 56.03 (4)° and the asscociated C-N-C angle is 125.71 (10)°. The guanidine-like C=N double bond is clearly localized, with a bond length of 1.2879 (14) Å. The C-S-C angle is 102.12 (5)° and the S-C(aromatic) and S-C bond lengths  ...[more]

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