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Cyclo-hexane-1,4-dicarb-oxy-lic acid-pyridinium-4-olate (1/1).

ABSTRACT: In the title adduct, C5H5NO·C8H12O4, the heterocycle exists in its zwitterionic form. The cyclo-hexane ring exhibits a chair conformation with the carb-oxy-lic acid groups in equatorial and axial orientations. In the crystal, mol-ecules are linked through charge-assisted O-H?O(-), N(+)-H?O(-) and N(+)-H?O hydrogen bonds, and an additional series of C-H?O contacts, giving a pleated two-dimensional hydrogen-bonded network parallel to (-204).

SUBMITTER: Cruz-Enriquez A

PROVIDER: S-EPMC3629634 | biostudies-literature | 2013 Apr

REPOSITORIES: biostudies-literature

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Cyclo-hexane-1,4-dicarb-oxy-lic acid-pyridinium-4-olate (1/1).

Cruz-Enríquez Adriana A Peinado-Guevara Hector J HJ Reyes-Marquez Viviana V Höpfl Herbert H Campos-Gaxiola José J JJ

Acta crystallographica. Section E, Structure reports online 20130328 Pt 4

In the title adduct, C5H5NO·C8H12O4, the heterocycle exists in its zwitterionic form. The cyclo-hexane ring exhibits a chair conformation with the carb-oxy-lic acid groups in equatorial and axial orientations. In the crystal, mol-ecules are linked through charge-assisted O-H⋯O(-), N(+)-H⋯O(-) and N(+)-H⋯O hydrogen bonds, and an additional series of C-H⋯O contacts, giving a pleated two-dimensional hydrogen-bonded network parallel to (-204). ...[more]

PMID: 23634121

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