The efficient desymmetrization of glycerol using scaffolding catalysis.
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ABSTRACT:
SUBMITTER: Giustra ZX
PROVIDER: S-EPMC3633631 | biostudies-literature | 2013 May
REPOSITORIES: biostudies-literature
Publications
The efficient desymmetrization of glycerol using scaffolding catalysis.
Giustra Zachary X ZX Tan Kian L KL
Chemical communications (Cambridge, England) 20130501 39
Glycerol is an ideal building block for the synthesis of complex molecules, because it is inexpensive and highly functionalized. We report the desymmetrization of glycerol through silyl transfer, using a chiral organic catalyst in high yield and enantioselectivity. ...[more]
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