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Methyl 3-(pyridin-4-yl-methyl-idene)di-thio-carbazate.

ABSTRACT: There are two independent mol-ecules in the asymmetric unit of the title mol-ecule, C8H9N3S2, both of which exhibit an E conformation with the pyridine ring and di-thio-carbazate fragment located on opposite sides of the C=N bond. The pyridine ring and di-thio-carbazate group are approximately coplanar, with dihedral angles of 4.74?(1) and 8.77?(1)° between their planes in the two mol-ecules. In the crystal, mol-ecules are linked to each other via N-H?N hydrogen bonds, forming zigzag chains parallel to [10-1].

SUBMITTER: Wang H

PROVIDER: S-EPMC3648245 | biostudies-literature | 2013 May

REPOSITORIES: biostudies-literature

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Methyl 3-(pyridin-4-yl-methyl-idene)di-thio-carbazate.

Wang Hui H Hossain Abul-Monsur-Showkot AM Wang Shi-Chao SC Tian Yu-Peng YP

Acta crystallographica. Section E, Structure reports online 20130413 Pt 5

There are two independent mol-ecules in the asymmetric unit of the title mol-ecule, C8H9N3S2, both of which exhibit an E conformation with the pyridine ring and di-thio-carbazate fragment located on opposite sides of the C=N bond. The pyridine ring and di-thio-carbazate group are approximately coplanar, with dihedral angles of 4.74 (1) and 8.77 (1)° between their planes in the two mol-ecules. In the crystal, mol-ecules are linked to each other via N-H⋯N hydrogen bonds, forming zigzag chains para ...[more]

PMID: 23723865

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