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Catalytic enantioselective allyl-allyl cross-coupling with a borylated allylboronate.


ABSTRACT: Catalytic enantioselective allyl-allyl cross-coupling of a borylated allylboronate reagent gives versatile borylated chiral 1,5-hexadienes. These compounds may be manipulated in a number of useful ways to give functionalized chiral building blocks for asymmetric synthesis.

SUBMITTER: Le H 

PROVIDER: S-EPMC3663875 | biostudies-literature | 2013 Apr

REPOSITORIES: biostudies-literature

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Catalytic enantioselective allyl-allyl cross-coupling with a borylated allylboronate.

Le Hai H   Kyne Robert E RE   Brozek Laura A LA   Morken James P JP  

Organic letters 20130319 7


Catalytic enantioselective allyl-allyl cross-coupling of a borylated allylboronate reagent gives versatile borylated chiral 1,5-hexadienes. These compounds may be manipulated in a number of useful ways to give functionalized chiral building blocks for asymmetric synthesis. ...[more]

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