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Catalytic stereospecific allyl-allyl cross-coupling of internal allyl electrophiles with AllylB(pin).

ABSTRACT: Application of internal electrophiles in catalytic stereospecific allyl-allyl cross-coupling enable the rapid construction of multisubstituted 1,5-dienes, including those with all carbon quaternary centers. Compounds with minimal steric differentiation can be synthesized with high enantiomeric excess.

SUBMITTER: Le H 

PROVIDER: S-EPMC3998767 | biostudies-literature | 2014 Apr

REPOSITORIES: biostudies-literature

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Catalytic stereospecific allyl-allyl cross-coupling of internal allyl electrophiles with AllylB(pin).

Le Hai H   Batten Amanda A   Morken James P JP  

Organic letters 20140404 8

Application of internal electrophiles in catalytic stereospecific allyl-allyl cross-coupling enable the rapid construction of multisubstituted 1,5-dienes, including those with all carbon quaternary centers. Compounds with minimal steric differentiation can be synthesized with high enantiomeric excess. ...[more]

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