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2-(Pyridin-4-yl)-1H-benzimidazole.

ABSTRACT: The title compound, C12H9N3, is an unhydrated analogue of the previously reported trihydrate. The mol-ecule is essentially planar, with a 3.62?(11)° angle between the pyridine and benzimidazole planes. In the crystal, N-H?N hydrogen bonds result in chains of mol-ecules parallel to [010], which are additionally linked by weak ?-? stacking inter-actions [centroid-centroid distance = 3.7469?(17)?Å], resulting in extended sheets of molecules parallel to (103).

SUBMITTER: Geiger DK

PROVIDER: S-EPMC3685029 | biostudies-literature | 2013 Jun

REPOSITORIES: biostudies-literature

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2-(Pyridin-4-yl)-1H-benzimidazole.

Geiger David K DK Bond Christopher J CJ

Acta crystallographica. Section E, Structure reports online 20130511 Pt 6

The title compound, C12H9N3, is an unhydrated analogue of the previously reported trihydrate. The mol-ecule is essentially planar, with a 3.62 (11)° angle between the pyridine and benzimidazole planes. In the crystal, N-H⋯N hydrogen bonds result in chains of mol-ecules parallel to [010], which are additionally linked by weak π-π stacking inter-actions [centroid-centroid distance = 3.7469 (17) Å], resulting in extended sheets of molecules parallel to (103). ...[more]

PMID: 23795048

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