Ontology highlight
ABSTRACT:
SUBMITTER: Cheng ZD
PROVIDER: S-EPMC3685068 | biostudies-literature | 2013 Jun
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20130518 Pt 6
The title compound, C20H47NO6Si4, was synthesized by per-O-tri-methyl-silylation of N-acetyl-d-glucosa-mine using chloro-tri-methyl-silane in the presence of hexa-methyl-disiloxane. The tri-methyl-silyl group and acetamido group are located on the same side of the pyran ring, showing an α-configuration glycoside. One of the tri-methyl-silyl groups is disordered over two orientations, with site-occupancy factors of 0.625 (9) and 0.375 (9). In the crystal, N-H⋯O hydrogen bonds link the mol-ecules ...[more]