Unknown

Dataset Information

0

N,N-Di-methyl-dehydro-abietyl-ammonium chloride ethanol monosolvate.


ABSTRACT: The title compound {systematic name: 1-[(1R,4aS,10aR)-7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octa-hydro-phenan-thren-1-yl]-N,N-di-methyl-methanaminium chloride ethanol monosolvate}, C22H36N(+)·Cl(-)·C2H6O, was synthesized from dehydroabietylamine by N-methyl-ation with formaldehyde/formic acid and transformation into the hydro-chloride. The de-hydro-abietyl moiety exhibits the usual conformation with the two cyclo-hexane rings in chair and half-chair conformations and a trans-ring junction. The crystal structure is built up from columns of the de-hydro-abietyl moieties stacked along the a axis. These columns are held together by the chloride ions via N-H⋯Cl and C-H⋯Cl inter-actions, which establish a two-dimensional network parallel to (010). The ethanol solvent mol-ecules are located between the columns and anchored via O-H⋯Cl hydrogen bonds.

SUBMITTER: Huang XZ 

PROVIDER: S-EPMC3685098 | biostudies-literature |

REPOSITORIES: biostudies-literature

Similar Datasets

| S-EPMC9462312 | biostudies-literature
| S-EPMC5730313 | biostudies-literature
| S-EPMC3050176 | biostudies-literature
| S-EPMC2961632 | biostudies-literature
| S-EPMC3772413 | biostudies-literature
| S-EPMC8647755 | biostudies-literature
| S-EPMC3998351 | biostudies-literature
| S-EPMC3884262 | biostudies-literature
| S-EPMC3998323 | biostudies-literature
| S-EPMC3684941 | biostudies-literature